A pressure sensitive adhesive is a permanently tacky substance that adheres to a given surface when light pressure is applied. A pressure sensitive adhesive maintains a fine balance between adhesion (holding power of the adhesive on external substrates) and cohesion (holding power of the combined internal components of the adhesive). PSAs do not require a chemical reaction to develop adhesion forces.
Adhesive: Typical adhesives are acrylic, natural rubber, or synthetic rubber. Special adhesives with a smaller application base are silicone, butyl, or EVA (ethylene - vinyl - acetate).
Backings: A backing (or carrier) is a relatively thin, flexible, webbased material. It can be made from various kinds of materials, such as paper, film, foil, foam, fabrics, non-wovens, and laminates. Backings are often chosen due to the function they fulfill, such as cushioning, dampening, maintaining a barrier, etc.
Primer: A primer is used to increase the holding power of the adhesive to the backing. The primer can be a liquid substance coated onto the backing material, or a physical treatment, such as corona or flame treatment. This is especially important if the tape needs to remove cleanly, or if the tape is stressed permanently with a load.
Release Liner: A release liner is mainly used with double sided tapes. Siliconized papers or films are the main types of release liners. The optimal liner choice depends on the application. If die-cut ability is required, polyester liners are preferable. If the tape is exposed to humidity, poly-coated papers are mainly used due to their dimensional stability. For most applications, paper liners are the liners of choice.
Release Coating: The backing of a single-sided tape, and the release liner for a double-sided tape, are treated with a release coating. The release coating ensures stable unwinding of the tape during the application. This is very important for automatic applications in which the tape can be unwound at high speeds. A release coating can have different release forces for either easy unwinding or harder unwinding, depending on the customer’s needs.
Adhesion: Adhesion is the attraction force between adhesive and substrate, which depends on the adhesive, the substrate, and the application conditions such as: application pressure, time period of pressure, and temperature during application.
Cohesion: Cohesion describes the inner strength of an adhesive. It is relevant for applications where the force, in effect, is parallel to the bonding area. High cohesion goes hand-inhand with high temperature resistance, low-edge picking, and high holding power or shear resistance.
Tack: Tack is the wetting capability of an adhesive to the substrate at first contact. Tack is effective under minimum pressure and for a short period of contact time. For most applications, tack is not relevant because time is required to press the tape to the substrate. For applications such as flying splices in the paper and print industry, tack is an important criterion. Tack also supports adhesion on rough surfaces. The thumb test is often used to characterize an adhesive, even though it gives no indication of the adhesion or the overall tape performance.
Shear: Shear is the ability of an adhesive to resist creep or slippage.
Tensile Strength: Tensile strength is mainly important for single-sidedtapes where the backing for the particular application has to withstand tensile stress. Carton sealing tapes or strapping/bundling applications are most important. The tensile strength of tape is usually not important for double-sided tapes, as long as the bonding materials are not stretchable.
Elongation: Elongation is the percentage in which a tape can be stretched prior to breaking.
Single-Sided Tape
For single-sided tapes, the backing can be comprised of a variety of flat web-based materials, such as film, paper, foil, fabrics, or foam. In many instances, the backing is treated with a release coating to enable stable unwinding forces, or with a primer to ensure that the adhesive sticks to the correct side of the backing.
For double-sided tapes, the backing is coated with a pressure sensitive adhesive on both sides. The backing materials can be the same as any of those mentioned for single-sided tapes. A release liner is utilized to prevent the adhesives from sticking to themselves. The release liner is normally a siliconecoated paper or filmic material.
A transfer tape is considered a specialty product, as it does not harbor a backing material. The pressure sensitive adhesive is coated onto the release liner and wound onto a roll. A release liner is always part of the transfer tape structure.
As the name indicates, pressure sensitive tapes need pressure to ensure bonding. The recommended bonding pressure is 14.5 – 29 psi =^ 10 – 20 N/cm². The pressure is needed to ensure that the tape comes in close contact to the surface so that the physical forces between the adhesive and the surface can build up. The tape should be applied at moderate temperatures between 59º F and 95º F. Lower temperatures might lead to insufficient “wetting” (coverage) of the adhesive on the substrate. Extremely high temperatures might cause the tape to stretch when being applied, which could create additional stress in the final application.
Surface Preparation : The surface to which the tape is applied should be clean, dry,and free of oils or grease. To properly clean the surface, a “lintless” cloth should be used. Suitable solvents for use include benzenes, alcohols, esters, and ketones. Ensure that the substrate is able to withstand the solvent prior to application.
Surface Energy/Tension: To ensure the best possible adhesion, it is optimal that the surface onto which the tape is applied has a higher surfaceenergy or polarity than the tape’s adhesive system.
There are some substrates that are generally easier to bond to than others. These are the materials with higher surface tension/energy. It is important to know that coatings on the surfaces or fillers in the substrates might influence the adhesion characteristics. A painted aluminum or plasticized PVC (polyvinyl chloride) might display completely different bonding characteristics as compared to pure, unaltered materials.
To increase the surface tension of substrates with low-surface energy, consider using a primer or adhesion promoter. Corona or flame treatments can also be applied. It is critical that adhesive systems and primers are cooperative in nature. Testing is, of course, always critical to ensure the desired result.
Pressure sensitive tapes need to be stored under defined conditions.
Extreme high temperatures can lead to degradation of the adhesive or backing materials. Extreme low temperatures might influence the bonding characteristics.
The recommended storage conditions are:
Traditional Production Process
The ingredients – adhesive, resin, filler, and other additives are mixed with organic solvents or water.
The solved adhesive is transported to the coating device, after which the adhesive is coated in an even layer onto the backing and dried in the drying channel until all the solvents have evaporated. The result is a long roll of tape. After the coating process, the long rolls are converted into the desired roll sizes.
Hot-Melt Process
In the hot-melt process, the adhesive and other ingredients are processed without solvents. Due to heat in the process, the adhesive remains in a liquid state to be coated.
These tapes are engineered to perform at the highest levels for their given applications. There are, however, additional factors that ultimately determine a tape's true holding power in any circumstance, which include:
To ensure maximum surface contact of the tape to substrate, it is critical that the bonding surface is completely clean and free of dust, dirt, or any other debris. Additionally, a slight texture to the surface can actually aid the adhesive "wetting out" (coverage) process, helping to ensure a maximum bond.
Once the tape is adhered to the surface, it is optimal to allow the tape's adhesive system a period of time to completely penetrate the surface. For acrylic adhesive systems, desired dwell time ranges from 12 hours to up to three days.
One of the most important factors to consider when choosing the right tape relates to the environmental conditions of the application. Adhesive systems are designed very specifically to accommodate a range of conditions, including indoor vs. outdoor; humid vs. dry; ultraviolet light exposure, etc.
If the application calls for a double-sided tape to secure components that have more than nominal weight, it is critical to determine the exact weight dimensions, including short-term and long-term requirements, in order to determine the best tape for the job. In most cases, a tape with an acrylic adhesive system will be the answer.
In today’s advanced information age, a common search for the term “Pressure-Sensitive Tape” will likely result in a response similar to this: Wikipedia, (the free encyclopedia) – The tape consists of a pressure-sensitive adhesive coated onto a backing material such as paper, plastic film, cloth, or metal foil. Some have a removable release liner which protects the adhesive until the liner is removed.
Some have layers of adhesives, primers, easy release materials, filaments, printing, etc. made for specific functions. Descriptions such as this, however, fail to capture the important role that each of these elements play with regard to today’s advanced pressure-sensitive adhesive tapes. While all tape components are important when determining performance, this article will offer a closer look at the all-important tape backing systems.
In years past, the main function of a tape backing, otherwise known as a “carrier”, was to “carry” the adhesive to its point of use. Today, tape backings are most often highly engineered and essential components of the overall tape solution. Today’s backings are designed to withstand certain forces or to split at an exact defined force; to be optically clear or reflective; to be permeable or to function as a barrier (e.g. for humidity or oxygen); to be very thin (1.5 μm = 0.059 mils) or to be very thick (>3mm or 118 mils); to serve as gap fillers and / or noise dampeners; and to enable the tape to be machine-processed and / or die-cut. These functions are merely a few examples of the variety of functions modern tape backings can fulfill.
Due to the multiplicity of the available types of backings, it is worthwhile to discuss features and benefits of the different types.
Paper backings are mainly used for masking applications. They are easy to tear by hand; allow for good conformability to a variety of surfaces; offer good temperature and solvent resistance; and they are environmentally compatible. Higher degree of “crepe” to the paper allows for easier application of the tape to curves and contours. It is important that the paper be paintable, otherwise the paint would not stick to the backing, and there is the risk that recently painted areas would be unintentionally contaminated. There are more complex paper backings which are used in the paper industry for splicing or end tabbing large paper rolls. In this application, the paper needs to be repulpable (dissolvable without leaving any residues in the newly produced paper).
The most used filmic backings are:
Let’s take a closer look at each type:
Generally speaking, PVC backings typically exude the following characteristics: durability, low flammability, printable, can be embossed, weather resistant albeit temperature sensitive. PVC can be produced in both rigid and soft configurations. Rigid PVC is mainly used as the backing of choice for carton sealing tapes. Soft PVC is most often used as backing for insulating tapes and masking tapes, allowing for the flexibility of applying to curves and contours.
These two backings – PolyEthylene and PolyPropylene - are the environmental friendly alternatives to PVC. PE offers low cost, good flexibility, and due to its softness, a high conformability. PP is a mono-axial-oriented film (MoPP), meaning that it supplies strength in only one direction, as compared to bi-axial-oriented film (BoPP) that offers strength in two directions, along with other various advantages. MoPP shows very high tensile strength (in mid-direction) and low elongation (in mid-direction), but also low tensile strength (in cross-direction). This makes this backing ideal for strapping and bundling applications, as well as for packaging applications that utilize tear strips. BoPP backings offer low-cost, high-tear resistance in mid-direction and cross-direction, extreme flatness, and wellbalanced mechanical properties.
Polyester backings are mostly used as BoPET (bi-axial-oriented polyester). PET is available in a very wide range of thicknesses (1.5μm to 500μm / .059 mils – 19.68 mils). The advantages of polyester include high-temperature resistance and high UV (ultraviolet) stability. It is the preferred backing for die-cutting processes, and therefore, it is one of the most commonly used backings in the PSA (pressure-sensitive adhesive) industry.
In addition to performing the function of bonding two parts together, PE foam tapes are often used for a variety of reasons:
Application examples for foam tapes are endless; specific examples include bonding plastic emblems onto metal substrates (Automotive Industry), or bonding muntin bars on windows, or in many other highend applications. In flexographic printing applications, the foam tape not only holds the printing plate onto printing cylinders / sleeves, but also defines the print quality by its hardness / softness level, as well as altering the possible printing speed by its elasticity and recovery (memory) rate. The faster the foam recovers, the higher the possible printing speed.
Additionally, since some print jobs are very long, the foam performance must maintain its stability throughout thousands of impressions. Closed-cell PE foams have proven to be very suitable for most applications. As PolyEthylene has a low-melting temperature; the application for PE foams is limited to temperatures below 200ºF.
For high-temperature applications (above 200ºF), or for applications that require even higher performance than a foam tape can offer, Acrylic Core Backings are the high-end solution. Due to the fact that the backing is made of an acrylic polymer, the backing has outstanding visco-elastic characteristics. In simple terms, the backing is able to dissipate stress, which leads to a much higher performance than “normal” backings. Additionally, the visco-elastic property of the acrylic core backing is capable of compensating for different thermal expansions in a much higher degree than a PE foam tape. Evaluations have shown that, depending on the backing structure, the thermal compensation can achieve three times the thickness of the tape. Combined with the very high bonding strength, acrylic core tapes are the ideal solution for bonding differing substrates such as glass to metal, or metal to plastic. As an added benefit, acrylic backings are very resistant to many environmental elements, such as sunlight, ozone, temperature, and water. These characteristics make acrylic core tapes the ideal choice for long-lasting, high-performance outdoor applications. Application examples include bonding body side moldings to car bodies (automotive); bonding framing of flat screens (electronics); bonding glass panels to metal frames; or joining photovoltaic panels onto back rails (solar panels). These and other appropriate applications demand high-bonding strength, long-term (up to 25 years) outdoor performance, and compensation
In conclusion, when specifying your next adhesive tape application, take the tape backing’s features / characteristics into account. A good backing choice can put you in front of the competition!
When considering the components that affect the performance of pressure-sensitive adhesive (PSA) tapes, it is vital to glean an understanding of the adhesive systems that are most often incorporated in the tape production process. In this article, we will explore varying types of adhesive systems and the unique characteristics of each.
When considering the components that affect the performance of pressure-sensitive adhesive (PSA) tapes, it is vital to glean an understanding of the adhesive systems that are most often incorporated in the tape production process. In this article, we will explore varying types of adhesive systems and the unique characteristics of each.
There are three primary groups of adhesives that encompass the lionʼs share of adhesives used in PSA production. These three groups are: natural rubber adhesives, synthetic rubber adhesives, and acrylic adhesives. Within these groups, there are countless variations and distinctive features. As such, it is not possible to predict the exact performance of an adhesive simply by knowing the type of adhesive. There are, however, specific characteristics that are typical of every adhesive type, and being aware of them can prevent making the wrong tape decision for the specific application.
Natural rubber (NR) is the first known adhesive technology used with PSAs. The biggest and perhaps most well-known use of natural rubber is in the production of car tires. NR by its very nature is not tacky, nor is it an adhesive. Tackifier resins are always added to NR to create a PSA. A key advantage of NR is a bi-product of one of its characteristics: very long polymer chains that are entangled with each other. This feature allows the natural rubber to be very flexible,even at lower temperatures, due to the length of the polymer. Additionally, the entanglement of the polymers creates an inner strength of the NR.
These characteristics allow for a wide-application window for NR adhesives. The type of rubber used, the compounded resins, and other ingredients determine the performance of the NR adhesive. As a general rule, natural rubber PSAs offer the following advantages:
NR adhesives have some disadvantages, which are important to know when determining whether or not the product is suitable for the specific application:
For many non-permanent, especially indoor applications, NR adhesives are an excellent choice.
There are several synonyms for synthetic rubber(SR) adhe-sives, such as SBS, SIS, or SEBS. The SR polymer for adhesives shows a very unique molecular structure. There are two hard-end segments (Styrene) and a softer, rubbery middle segment (Butadiene), so the structure is: Styrene – Butadiene – Styrene = SBS.
The styrene-end segment determines the cohesiveness (internal strength) of the adhesive; the rubbery middle segment determines the adhesiveness. By itself, SR does not harbor any adhesive properties. To create a PSA, tackifier resins need to be added. In contradiction to natural rubber polymers, the SR polymer has a short length and a low molecular weight.
The advantages of SR adhesives are:
The disadvantages of SR adhesives are:
Acrylic adhesives are industrially produced by polymerization, otherwise known as a customized formulation. Adhesive properties of acrylic can be adjusted and controlled by manipulating the selection of monomers used in the formulation, as well as the polymerization process. In contradiction to NR and SR adhesives, acrylic adhesives are tacky by nature. Acrylic adhesives have long polymer chains that are cross-linked. This cross-linking feature catapults acrylic adhesives into a much higher performance category than both natural rubber and synthetic rubber adhesives.
The advantages of acrylic PSAs are:
Disadvantages are:
To create acrylic PSAs with increased immediate peel adhesion or reduced dwell time, tackifier resins are often added to the acrylic polymer. The addition of resins, however, will change the cohesiveness of the acrylic adhesive. Due to the fact that the acrylic adhesive is cross-linked and shows excellent resistance to aging and temperature, acrylics are the best adhesive solution for long-term, outdoor applications.
Aside from the three major types of adhesives used in tape production, there are a few lesser used and lesser known types of adhesives on the market, such as: